【内容简介】
This is the fifth of a five-volume comprehensive reference work that provides commputer simulation and modeling techniques in various fields of chemical sensing ,the importand applicaions for chemical sensing include such topics as bulk and surface diffusion,adsorption,surface reactions,sintering,conductivity,mass transport and interphase interactions.
【目 录】
PREFACE
ABOUT THE EDITOR
CONTRIBUTORS
PART I: SOLID—STATE ELEDTROCHEMICAL SENSORS
SURFACE AND INTERFACE DEFETS m lomc CRYSTALS
N. F. Uvarov
1 Introduction
1.1 Solid Electrolytes and Electrodes for Electrochemical Sensors:
A Brief Overview
1.2 Surface and Interface Properties of Ionic Solids
2 Calculation of the Surface Potential and Surface Defects Using the
Stem Model
2.1 Description of the Model
2.2 PureCrystalsof the NaC1 Type
2.3 Surface Potential in NaC1CrystalsContaining Divalent Cations
2.4 Comparison with Experimental Data
2.5 Surface Potential and Concentration of Point Defects on Grain
Boundaries of Superionic Oxide Ceramics
2.6 Surface Disorder in Terms of Energy Diagrams
2.7 Defects on Interfaces
3 Size Effects in Nanocomposite Solid Electrolytes
4 Applications in Sensors
5 Conclusions
References
2. SOLID—STATE ELECTROCHEMICAL GAS SENSORS
C. O. Park
I. Lee
D. R. Lee
J. W. Fergus
N. Miura
H. J. Yoo
1 Introduction
2 Electrode Potentials
3 Types of Electrochemical Sensors
3.1 Equilibrium Potentiometric Sensors
3.2 Mixed Potentiometric Sensors
3.3 Amperometric Sensors
4 Applications
4.1 Oxygen Sensors
4.2 Carbon Dioxide Sensors
4.3 NOx Sensors
4.4 SOx Sensors
4.5 Hydrogen Sensors
Acknowledgments
References
PART 2: ELECTROCHEMICAL SENSORS FOR LIQUID ENVIRONMENTS
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